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Ethylene Industry(C2)

ETX (Ethoxylation) Plant

Ethoxylates are versatile surfactants widely used for their emulsifying, dispersing, wetting, and solubilizing properties. Key applications include household and personal care products (e.g., detergents, shampoos), textile auxiliaries, agrochemical emulsifiers, pharmaceutical carriers (e.g., vaccine stabilizers), petroleum demulsifiers, and eco-friendly materials. By adjusting ethylene oxide (EO) addition numbers, their hydrophilic-lipophilic balance (HLB) can be tailored for diverse industrial needs, with current trends focusing on green alternatives (e.g., biodegradable variants) and high-performance grades (e.g., pharmaceutical purity).

Key Applications:

  1. Household & Personal Care

    • Detergents (e.g., fatty alcohol ethoxylates, AEOs for cleaning);

    • Shampoos/body washes (e.g., sodium laureth sulfate, SLES for foaming);

    • Skincare products (e.g., PEG stearate as emulsifiers).

  2. Textile Industry

    • Leveling agents (high-EO ethoxylated amines for uniform dyeing);

    • Scouring agents (low-EO alcohol ethers to remove oils).

  3. Agriculture & Pesticides

    • Pesticide emulsifiers (e.g., fatty acid methyl ester ethoxylates, FMEE as eco-friendly alternatives);

    • Fertilizer additives (enhancing leaf penetration).

  4. Petroleum & Industrial

    • Crude oil demulsifiers (phenolic resin ethoxylates for dehydration);

    • Metalworking fluids (reducing friction).

  5. Pharmaceuticals & Biotechnology

    • Drug carriers (e.g., Tween 80 for vaccine solubilization);

    • Lab reagents (e.g., Triton X-100 for cell lysis).

  6. Coatings & Construction

    • Aqueous paint dispersants (preventing pigment settling);

    • Concrete water reducers (improving flowability).

  7. Eco-Friendly & Emerging Fields

    • Biodegradable detergents (sugar-based ethoxylates);

    • Energy storage (battery electrolyte additives).

Core Feature: Tunable HLB via EO chain length (*n*-value) enables customized performance across applications.

Introduction

There are two trains in ETX production.
Train 1 is a three-pot system consisting of three independent sections:
Pre-Treatment: charging, catalysing, heating and drying.
Reaction with single loop: EO addition, cooling.
Post-Treatment: cooling, neutralization.
Any post-treatment, e.g. stripping.
Train 2 is a two-pot system consisting of two independent sections:
Reaction with dual-loop system: charging, catalysing, heating and drying, EO addition, cooling.
Post-Treatment: cooling, neutralization.
Any post-treatment, e.g. stripping.

Core Advantages of Batch Processes

  1. Flexibility and Adaptability

    • Multi-Product Capability: A single reactor can rapidly switch between different initiators (e.g., alcohols, phenols, amines) and EO addition numbers (*n* = 3–20+), meeting customized demands across industries (e.g., cosmetics, textiles, agrochemicals).

    • Cost-Effectiveness for Small Batches: Ideal for low-volume, high-variety production, avoiding material waste and energy inefficiencies caused by frequent transitions in continuous processes.

  2. Low Investment and Ease of Operation

    • Simple Equipment: Requires only basic reactors (1–10 m³) and instrumentation, with initial capital costs 30–50% lower than continuous processes.

    • High Process Tolerance: Accommodates raw material impurities by adjusting dehydration time, catalyst dosage, or reaction conditions.

  3. Reaction Controllability

    • Phased Parameter Control: Enables manual or semi-automatic regulation of EO feeding rates and temperature gradients to manage exothermic spikes or delayed reactions.


 Irreplaceability of Batch Processes

Despite the efficiency and narrow PDI advantages of continuous processes (e.g., tubular reactors), batch operations remain vital due to:

  • Customization Needs: Stepwise reactions for specialized products (e.g., block copolymers, end-group modified ethoxylates) are easier to implement.

  • Niche Market Suitability: Ideal for annual capacities <50,000 tons (e.g., high-end cosmetic additives), avoiding overcapacity risks of continuous lines.

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